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Inicio » Actividades I+D > Publicaciones 2008 > Di-μ-acetato-κ3O,O′:O;κ3O:O,O′-bis[(acet...
artículo con referato
"Di-μ-acetato-κ3O,O′:O;κ3O:O,O′-bis[(acetato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)cadmium(II)]"
M.A. Harvey, S. Baggio, M.T. Garland and R. Baggio
Acta Cryst. E 64(11) (2008) m1450
Abstract
The title compound, [Cd2(C2H3O2)4(C12H8N2)2], consists of dimeric units built up around a crystallographic symmetry centre. Each cadmium(II) unit is chelated by a 1,10-phenanthroline (phen) group and two acetate ligands, one of which also acts as a bridge, linking both seven-coordinated cadmium(II) centres. The crystal structure is governed by a single ππ interaction between stacked phen groups [centroid-centroid distance 3.5209 (11) Å], leading to a planar structure parallel to (010).
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