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Inicio » Actividades I+D > Publicaciones 2006 > Di-μ-sulfato-κ3O,O′:O″;κ3O,O′:O″-bis{aqu...
artículo con referato
"Di-μ-sulfato-κ3O,O′:O″;κ3O,O′:O″-bis{aqua[2,4,6-tris(2-pyridyl)-1,3,5-triazine-κ3N1,N2,N6]manganese(II)} tetrahydrate"
M.E. Díaz de Vivar, S. Baggio, M.T. Garland and R. Baggio
Acta Cryst. E 62(1) (2006) m141-m143
The title compound, [Mn2(SO4)2(C16H12N6)2(H2O)2]·4H2O, crystallizes as dimers built up around inversion centers. The Mn cation is seven-coordinated in the form of a pentagonal bipyramid, with three sulfate O atoms involved in its coordination (two equatorial and one axial). The sulfate species also bridge to the second Mn cation. The other three equatorial sites are occupied by N atoms from the tridentate 2,4,6-tris(2-pyridyl)-1,3,5-triazine ligand and the remaining axial site by a water molecule. This compound is isostructural with the previously reported Cd analog.
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